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991.
J. Veerman J.W. Post M. Saakes S.J. Metz G.J. Harmsen 《Journal of membrane science》2008,310(1-2):418-430
Both in electrodialysis and in reverse electrodialysis ionic shortcut currents through feed and drain channels cause a considerable loss in efficiency. Model calculations based on an equivalent electric system of a reverse electrodialysis stack reveal that the effect of these salt bridges could be reduced via a proper stack design. The critical parameters which are to be optimized are ρ/r and R/r, where ρ is the lateral resistance along the spacers, R is the resistance of the feed and drain channels between two adjacent cells, and r is the internal resistance of a cell. Because these two parameters are dimensionless, different stacks can be easily compared. The model is validated with two experimental stacks differing in membrane type and spacer thickness, one with large ionic shortcut currents and one where this effect is less. The loss in efficiency decreased from 25 to 5% for a well-designed stack. The loss of efficiency in reverse electrodialysis and in electrodialysis can be reduced with the aid of the design parameters presented in this paper. 相似文献
992.
993.
Lamination Design Optimization for Continuous Fiber Reinforced Composites of Variable Thicknesses北大核心CSCD 下载免费PDF全文
由于具备高的比强度、比刚度,利用连续纤维增强复合材料代替传统金属材料以实现结构轻量化正受到设计者们的广泛关注。然而,结构的复杂性给复合材料的铺层设计与优化带来了很大的挑战。针对航空用复合材料铺层设计约束多的问题,通过逐步构建设计变量准确表达结构的铺层信息。基于经典遗传算法框架,结合各设计变量特点,定义了铺层优化算法中的遗传算子,通过引入“修复”策略保证了每一代解都能满足设计约束,分布在可行域区间内。最后利用精英保留策略提高了算法的局部寻优能力,可以降低复杂复合材料结构铺层设计的计算成本。通过解决经典benchmark问题并与已有优化结果的比较,验证了前述铺层优化算法的全局、局部寻优能力,为工程实际中的复合材料铺层设计优化提供了理论支撑。 相似文献
994.
In this study, ultrasound assisted dispersive solid-phase micro extraction combined with spectrophotometry (USA-DSPME-UV) method based on activated carbon modified with Fe2O3 nanoparticles (Fe2O3-NPs-AC) was developed for pre-concentration and determination of safranin O (SO). It is known that the efficiency of USA-DSPME-UV method may be affected by pH, amount of adsorbent, ultrasound time and eluent volume and the extent and magnitude of their contribution on response (in term of main and interaction part) was studied by using central composite design (CCD) and artificial neural network-genetic algorithms (ANN-GA). Accordingly by adjustment of experimental conditions suggested by ANN-GA at pH 6.5, 1.1 mg of adsorbent, 10 min ultrasound and 150 μL of eluent volume led to achievement of best operation performance like low LOD (6.3 ng mL−1) and LOQ (17.5 ng mL−1) in the range of 25–3500 ng mL−1. In following stage, the SO content in real water and wastewater samples with recoveries between 93.27–99.41% with RSD lower than 3% was successfully determined. 相似文献
995.
Multiwalled carbon nanotubes (MWCNTs) were magnetized with Fe3O4 nanoparticles (MWCNTs-Fe3O4-NPs) and subsequently coated by vinyl end groups (Vinyltrimethoxysilane). MWCNT-Fe3O4-NPs were used as support for a new morphine (MO) molecularly imprinted polymer (MWCNT-Fe3O4-NPs@MO-MIP) by surface imprinting polymerization method. The MWCNT-Fe3O4-NPs@MO-MIP was characterized by FTIR, VSM and SEM techniques and successfully used for determination of MO. Ultrasonic-assisted magnetic solid phase extraction followed by UV–vis spectrophotometer (UAMSPE-UV–vis) was investigated for MWCNT-Fe3O4-NPs@MO-MIP and compared with non-imprinted polymer (NIP) using batch method. Central composite design under response surface methodology was used for the evaluation of the effect of variables, individually, as well as their possible interaction effects on the adsorption process. The variables such as sonication time, MWCNT-Fe3O4-NPs@MO-MIP mass, initial concentration of MO and pH were investigated in this study. At optimum experimental conditions, UAMSPE-UV–vis method was exhibited a linear range of 0.8–8.7 mg L−1 of the MO concentration with a detection limit of 0.18 mg L−1. The relative standard deviation for the analyte was found to be lower than 2.32%. The MWCNT-Fe3O4-NPs@MO-MIP adsorption capacity was found to be 37.01 mg g−1. The enrichment and preconcentration factors were found to be 107.01 and 98.21, respectively. The developed method was finally applied successfully to the determination of MO in urine and wastewater samples with the recoveries ranged from 96.40 to 105.6%. 相似文献
996.
目的研究逆转录酶的运动性和生理功能的关系,以及N-乙酰基-β-芳基-1,2-二脱氢乙胺类衍生化合物与其的分子识别,方法采用高斯网络模型和各向异性网络模型研究了p66和p66-DNA的运动模式差异,并用分子对接方法研究化合物与逆转录酶的识别.结果 DNA的结合对p66各区域的运动方向影响不大,但其运动的幅度大大降低.分子对接结果发现Y115和M184的疏水结构在识别的过程中起到重要作用.结论基于各个区域的运动方向分析,推测手指区和RNase H区的开合运动可能是逆转录酶发挥逆转录功能的重要原因.并且,N-乙酰基-β-芳基-1,2-二脱氢乙胺类衍生化合物的N-甲基取代和反式的双键结构更有利于与逆转录酶的识别 相似文献
997.
针对公司调度自动化机房网络配线无图纸管理和标签标识不规范的情况,自主研发了一套机房网络配线管理软件。首先,分析了配线可视化管理软件应对网络配线绘图和标签信息自动生成的功能需求,并运用MVC模式理论进行软件架构设计;其次,重点阐述了基于QT图形库的关键功能实现,包括核心图元类的构建、元件库组件可配置生成、图形序列化反序列操作、拓扑查找、设备图元属性管理及标签信息自动生成功能等;最后,通过举例说明该软件在实际机房管理中的使用方法和应用成效。应用结果表明,通过绘制整个机房的网络连接图并录入相关设备属性信息,有助于提高机房网络故障的诊断效率和降低机房系统的运维风险。 相似文献
998.
以LabVIEW14.0为虚拟仪器软件开发平台,采用生产者/消费者设计模式的控制策略、技术数据管理流(TDMS)二进制文件储存策略和SQL数据库及事件结构相结合的实时更新策略,设计了集实时信息采集、储存、显示等功能于一体的应力波采集系统;3种控制策略相结合,解决了传统顺序结构设计模式下程序循环周期长、执行效率低的问题,而且解决了实时采集过程中数据的快速、大容量储存问题,实现了采集过程中采集参数的实时更新;实验结果表明该应力波采集系统具有响应速度快、执行效率高等优点。 相似文献
999.
1000.
Highly Contorted 1,2,5‐Thiadiazole‐Fused Aromatics for Solution‐Processed Field‐Effect Transistors: Synthesis and Properties 下载免费PDF全文
Xin Shi Shuli Liu Chunming Liu Yueming Hu Saihua Shi Dr. Nina Fu Dr. Baomin Zhao Prof. Dr. Zhaohui Wang Prof. Dr. Wei Huang 《化学:亚洲杂志》2016,11(15):2188-2200
A straightforward strategy has been used to construct 1,2,5‐thiadiazole‐fused 12‐ring π systems through twofold Stille coupling and subsequent cyclodehydrogenation by utilizing the building blocks of naphthodithiophene and 5,6‐substituted benzo[b]‐2,1,3‐thiadidazole. Molecules 1 a and 1 b , which exhibit highly contorted π surfaces, show a butterfly‐shaped conformation according to DFT calculations. Within the molecules, a plane‐to‐plane angle of 44.8° was found. UV/Vis absorption, thermogravimetric analysis, differential scanning calorimetry, and cyclic voltammetry (CV) were used to study their physical properties. Strong intermolecular interactions of the nonplanar molecules were also observed by concentration‐dependent 1H NMR spectroscopy measurements and thin‐film XRD characterization. The low‐lying LUMO and high‐lying HOMO levels of the molecules are ?3.73 and ?5.48 eV, respectively, as estimated from CV measurements; this indicates their potential as semiconducting materials for solution‐processed organic field‐effect transistors (OFETS). A field‐effect hole mobility of up to 0.035 cm2 V?1 s?1, a threshold voltage of 6.98 V, and a current on/off ratio of 8.65×105 in air for 1 a have been demonstrated with the top‐contact bottom‐gate field‐effect transistor device structures; this represents an important step toward the solution‐processed OFET application of contorted aromatics. 相似文献